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At 16, she began transitioning to more adult roles with American Beauty, which went on to win the Academy Award For Best Picture in 2000.
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If he's reading this, and it's safe to say he is, the two aforementioned films should be available somewhere.
Shu Qi 20th Century Fox While her name may not be as well known as the aforementioned, Qi featured in a very big movie with a certain Jason Statham - yes, in The Transporter.